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Awual, M. R.; Hasan, M. M.*; Shahat, A.*
Sensors and Actuators B; Chemical, 203, p.854 - 863, 2014/11
被引用回数:176 パーセンタイル:99.19(Chemistry, Analytical)In this study, we designed ligand immobilized mesoporous adsorbent for ultra-trace Pb(II) monitoring and removal from wastewater. This adsorbent exhibited the large surface area-to-volume ratios and uniformly shaped pores in case cavities, and its active sites kept open functionality to taking up Pb(II). The data revealed that the adsorbent was able to detect the ultra-trace Pb(II) ions with high sensitivity and selectivity by charge transfer transduction mechanism. Then the adsorbent proved to have an efficient ability for continuous Pb(II) monitoring and removal even on-site and in situ chemical analyses.
Awual, M. R.; Hasan, M. M.*
Microporous and Mesoporous Materials, 196, p.261 - 269, 2014/09
被引用回数:223 パーセンタイル:99.57(Chemistry, Applied)Lead (Pb(II)) is a very toxic heavy metal that even at low concentration can affect living organisms. Therefore, designing effective materials with high selectivity and cost efficiency is essential for the control capturing of toxic Pb(II) ions. This study developed a ligand based conjugate adsorbent for simultaneous Pb(II) detection and removal from water samples. The experiment conditions were optimized based on contact time, solution acidity, initial Pb(II) concentration and pH value and diverse metal salt concentrations. The presence of other cations and anions did not adversely affect the Pb(II) capturing by the adsorbent. The maximum sorption capacity was determined to be as high as 195.31 mg/g.